{"id":4461,"date":"2023-05-18T10:08:48","date_gmt":"2023-05-18T08:08:48","guid":{"rendered":"https:\/\/gpt-dev.i3a.es\/?p=4461"},"modified":"2023-05-18T12:29:46","modified_gmt":"2023-05-18T10:29:46","slug":"hans-heinrich-carstensen","status":"publish","type":"post","link":"https:\/\/gpt.i3a.es\/es\/hans-heinrich-carstensen\/","title":{"rendered":"Hans Heinrich Carstensen"},"content":{"rendered":"<div id=\"pl-gb4461-69ef03d6bb16c\"  class=\"panel-layout\" ><div id=\"pg-gb4461-69ef03d6bb16c-0\"  class=\"panel-grid panel-has-style\" ><div class=\"siteorigin-panels-stretch panel-row-style panel-row-style-for-gb4461-69ef03d6bb16c-0\" data-stretch-type=\"full-width-stretch\" ><div id=\"pgc-gb4461-69ef03d6bb16c-0-0\"  class=\"panel-grid-cell\" ><div id=\"panel-gb4461-69ef03d6bb16c-0-0-0\" class=\"so-panel widget widget_sow-hero panel-first-child panel-last-child\" data-index=\"0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-hero so-widget-sow-hero-default-93415d0e2dbf-4461 so-widget-fittext-wrapper\"\n\t\t\t data-fit-text-compressor=\"0.85\"\n\t\t>\t\t\t\t<div class=\"sow-slider-base\" style=\"display: none\" tabindex=\"0\">\n\t\t\t\t\t<ul\n\t\t\t\t\tclass=\"sow-slider-images\"\n\t\t\t\t\tdata-settings=\"{&quot;pagination&quot;:true,&quot;speed&quot;:800,&quot;timeout&quot;:8000,&quot;paused&quot;:false,&quot;pause_on_hover&quot;:false,&quot;swipe&quot;:true,&quot;nav_always_show_desktop&quot;:&quot;&quot;,&quot;nav_always_show_mobile&quot;:&quot;&quot;,&quot;breakpoint&quot;:&quot;780px&quot;,&quot;unmute&quot;:false,&quot;anchor&quot;:null}\"\n\t\t\t\t\t\t\t\t\t\tdata-anchor-id=\"\"\n\t\t\t\t>\t\t<li class=\"sow-slider-image\" style=\"visibility: visible;;background-color: #1e73be\" >\n\t\t\t\t\t<div class=\"sow-slider-image-container\">\n\t\t\t<div class=\"sow-slider-image-wrapper\">\n\t\t\t\t<h3 style=\"text-align: center\"><a href=\"..\/team\/\">Investigadores<\/a><\/h3>\n<h1 style=\"text-align: center\"><strong>Hans Heinrich Cartensen<\/strong><\/h1>\n\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<\/li>\n\t\t<\/ul>\t\t\t\t<ol class=\"sow-slider-pagination\">\n\t\t\t\t\t\t\t\t\t\t\t<li><a href=\"#\" data-goto=\"0\" aria-label=\"mostrar diapositiva 1\"><\/a><\/li>\n\t\t\t\t\t\t\t\t\t<\/ol>\n\n\t\t\t\t<div class=\"sow-slide-nav sow-slide-nav-next\">\n\t\t\t\t\t<a href=\"#\" data-goto=\"next\" aria-label=\"diapositiva siguiente\" data-action=\"next\">\n\t\t\t\t\t\t<em class=\"sow-sld-icon-thin-right\"><\/em>\n\t\t\t\t\t<\/a>\n\t\t\t\t<\/div>\n\n\t\t\t\t<div class=\"sow-slide-nav sow-slide-nav-prev\">\n\t\t\t\t\t<a href=\"#\" data-goto=\"previous\" aria-label=\"diapositiva anterior\" data-action=\"prev\">\n\t\t\t\t\t\t<em class=\"sow-sld-icon-thin-left\"><\/em>\n\t\t\t\t\t<\/a>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div><\/div><\/div><\/div><\/div><\/div><\/div>\n\n<div id=\"pl-gb4461-69ef03d6bbc72\"  class=\"panel-layout\" ><div id=\"pg-gb4461-69ef03d6bbc72-0\"  class=\"panel-grid panel-no-style\" ><div id=\"pgc-gb4461-69ef03d6bbc72-0-0\"  class=\"panel-grid-cell\" ><div id=\"panel-gb4461-69ef03d6bbc72-0-0-0\" class=\"so-panel widget widget_sow-image panel-first-child panel-last-child\" data-index=\"0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-image so-widget-sow-image-default-8b5b6f678277-4461\"\n\t\t\t\n\t\t>\n<div class=\"sow-image-container\">\n\t\t<img \n\tsrc=\"https:\/\/gpt.i3a.es\/wp-content\/uploads\/2023\/05\/hans2020-e1603377566597-360x270-1-300x225.jpg\" width=\"300\" height=\"225\" srcset=\"https:\/\/gpt.i3a.es\/wp-content\/uploads\/2023\/05\/hans2020-e1603377566597-360x270-1-300x225.jpg 300w, https:\/\/gpt.i3a.es\/wp-content\/uploads\/2023\/05\/hans2020-e1603377566597-360x270-1-16x12.jpg 16w, https:\/\/gpt.i3a.es\/wp-content\/uploads\/2023\/05\/hans2020-e1603377566597-360x270-1.jpg 360w\" sizes=\"(max-width: 300px) 100vw, 300px\" title=\"hans2020-e1603377566597-360&#215;270\" alt=\"\" \t\tclass=\"so-widget-image\"\/>\n\t<\/div>\n\n<\/div><\/div><\/div><div 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https:\/\/gpt.i3a.es\/wp-content\/uploads\/2020\/10\/linkedin-12x12.png 12w\" sizes=\"auto, (max-width: 37px) 100vw, 37px\" \/>\t\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t<div class=\"sow-image-grid-image\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t<a href=\"#\"\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\ttarget=\"_blank\" \t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\trel=\"noopener noreferrer\" \t\t\t\t\t\t\t\t\t\t\t>\n\t\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"37\" height=\"37\" src=\"https:\/\/gpt.i3a.es\/wp-content\/uploads\/2020\/10\/website.png\" class=\"sow-image-grid-image_html\" alt=\"\" title=\"\" srcset=\"https:\/\/gpt.i3a.es\/wp-content\/uploads\/2020\/10\/website.png 37w, https:\/\/gpt.i3a.es\/wp-content\/uploads\/2020\/10\/website-12x12.png 12w\" sizes=\"auto, (max-width: 37px) 100vw, 37px\" \/>\t\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t<div class=\"sow-image-grid-image\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t<a href=\"#\"\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\ttarget=\"_blank\" \t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\trel=\"noopener noreferrer\" \t\t\t\t\t\t\t\t\t\t\t>\n\t\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"37\" height=\"37\" src=\"https:\/\/gpt.i3a.es\/wp-content\/uploads\/2020\/10\/google-scholar.png\" class=\"sow-image-grid-image_html\" alt=\"\" title=\"\" srcset=\"https:\/\/gpt.i3a.es\/wp-content\/uploads\/2020\/10\/google-scholar.png 37w, https:\/\/gpt.i3a.es\/wp-content\/uploads\/2020\/10\/google-scholar-12x12.png 12w\" sizes=\"auto, (max-width: 37px) 100vw, 37px\" \/>\t\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t<\/div>\n<\/div><\/div><\/div><div id=\"panel-gb4461-69ef03d6bbc72-0-1-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"2\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<blockquote>\n<p><strong>Tel\u00e9fono:<\/strong> +34 876 555042<\/p>\n<p><strong>Email:<\/strong> hcarsten@unizar.es<\/p>\n<p><strong>Address: <\/strong>Oficina CB1-0-2 Edificio Torres Quevedo C\/ Mar\u00eda de Luna 2 50018 Zaragoza Spain<strong><br \/>\n<\/strong><\/p>\n<\/blockquote>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div>\n\n<div id=\"pl-gb4461-69ef03d6bd987\"  class=\"panel-layout\" ><div id=\"pg-gb4461-69ef03d6bd987-0\"  class=\"panel-grid panel-has-style\" ><div class=\"panel-row-style panel-row-style-for-gb4461-69ef03d6bd987-0\" ><div id=\"pgc-gb4461-69ef03d6bd987-0-0\"  class=\"panel-grid-cell\" ><div id=\"panel-gb4461-69ef03d6bd987-0-0-0\" class=\"so-panel widget widget_sow-headline panel-first-child\" data-index=\"0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-headline so-widget-sow-headline-default-244eb6bef45a-4461\"\n\t\t\t\n\t\t><div class=\"sow-headline-container\">\n\t\t\t\t\t\t\t<h5 class=\"sow-headline\">\n\t\t\t\t\t\tSOBRE M\u00cd\t\t\t\t\t\t<\/h5>\n\t\t\t\t\t\t\t\t\t\t\t<div class=\"decoration\">\n\t\t\t\t\t\t<div class=\"decoration-inside\"><\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n<\/div><\/div><div id=\"panel-gb4461-69ef03d6bd987-0-0-1\" class=\"so-panel widget widget_sow-editor\" data-index=\"1\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t><h3 class=\"widget-title\">Research Interests<\/h3>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p>Kinetic analysis of complex gas phase reactions related to environmental chemistry, pyrolysis and combustion. I have a background as experimentalist (laser photolysis \/ LIF detection; low pressure flame studies using MBMS techniques or flow reactors combined with GC analysis) but work recently mainly on ab initio calculated thermochemistry. The objective of my current research is to develop software that automatically generated concise but complete reaction networks for predetermined conditions using a rate-based criterion for reaction selection.<\/p>\n<\/div>\n<\/div><\/div><div id=\"panel-gb4461-69ef03d6bd987-0-0-2\" class=\"so-panel widget widget_sow-image panel-last-child\" data-index=\"2\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-image so-widget-sow-image-default-c67d20f9f743-4461\"\n\t\t\t\n\t\t>\n<div class=\"sow-image-container\">\n\t\t<img \n\tsrc=\"https:\/\/gpt.i3a.es\/wp-content\/uploads\/2023\/05\/Sin-titulo.png\" width=\"409\" height=\"160\" srcset=\"https:\/\/gpt.i3a.es\/wp-content\/uploads\/2023\/05\/Sin-titulo.png 409w, https:\/\/gpt.i3a.es\/wp-content\/uploads\/2023\/05\/Sin-titulo-300x117.png 300w, https:\/\/gpt.i3a.es\/wp-content\/uploads\/2023\/05\/Sin-titulo-18x7.png 18w\" sizes=\"(max-width: 409px) 100vw, 409px\" title=\"Sin t\u00edtulo\" alt=\"\" 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type=\"hidden\" name=\"trp-form-language\" value=\"es\"\/><\/form><div class=\"tablenav\"><div class=\"tablenav-pages\"><span class=\"displaying-num\">18 registros<\/span> <a class=\"page-numbers button disabled\">&laquo;<\/a> <a class=\"page-numbers button disabled\">&lsaquo;<\/a> 1 de 4 <a href=\"https:\/\/gpt.i3a.es\/es\/hans-heinrich-carstensen\/?limit=2&amp;tgid=&amp;yr=&amp;type=&amp;usr=&amp;auth=&amp;tsr=#tppubs\" title=\"p\u00e1gina siguiente\" class=\"page-numbers button\">&rsaquo;<\/a> <a href=\"https:\/\/gpt.i3a.es\/es\/hans-heinrich-carstensen\/?limit=4&amp;tgid=&amp;yr=&amp;type=&amp;usr=&amp;auth=&amp;tsr=#tppubs\" title=\"\u00faltima p\u00e1gina\" class=\"page-numbers button\">&raquo;<\/a> <\/div><\/div><div class=\"teachpress_publication_list\"><h3 class=\"tp_h3\" id=\"tp_h3_2022\">2022<\/h3><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Gil-Lalaguna, Noem\u00ed;  Navarro-Gil, \u00c1frica;  Carstensen, Hans-Heinrich;  Ruiz, Joaqu\u00edn;  Fonts, Isabel;  Ceamanos, Jes\u00fas;  Murillo, Mar\u00eda Benita;  Gea, Gloria<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('149','tp_links')\" style=\"cursor:pointer;\">CO2 adsorption on pyrolysis char from protein-containing livestock waste: How do proteins affect?<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Science of The Total Environment, <\/span><span class=\"tp_pub_additional_volume\">vol. 846, <\/span><span class=\"tp_pub_additional_pages\">pp. 157395, <\/span><span class=\"tp_pub_additional_year\">2022<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 0048-9697<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_149\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('149','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_149\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('149','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_149\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('149','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_149\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{Gil-Lalaguna2022,<br \/>\r\ntitle = {CO2 adsorption on pyrolysis char from protein-containing livestock waste: How do proteins affect?},<br \/>\r\nauthor = {Noem\u00ed Gil-Lalaguna and \u00c1frica Navarro-Gil and Hans-Heinrich Carstensen and Joaqu\u00edn Ruiz and Isabel Fonts and Jes\u00fas Ceamanos and Mar\u00eda Benita Murillo and Gloria Gea},<br \/>\r\ndoi = {10.1016\/J.SCITOTENV.2022.157395},<br \/>\r\nissn = {0048-9697},<br \/>\r\nyear  = {2022},<br \/>\r\ndate = {2022-11-01},<br \/>\r\nurldate = {2022-11-01},<br \/>\r\njournal = {Science of The Total Environment},<br \/>\r\nvolume = {846},<br \/>\r\npages = {157395},<br \/>\r\npublisher = {Elsevier},<br \/>\r\nabstract = {Biogas generation through anaerobic digestion provides an interesting opportunity to valorize some types of animal waste materials whose management is increasingly complicated by legal and environmental restrictions. To successfully expand anaerobic digestion in livestock areas, operational issues such as digestate management must be addressed in an economical and environmentally sustainable way. Biogas upgrading is another necessary stage before intending it to add-value applications. The high concentration of CO2 in biogas results in a reduced caloric value, so the removal of CO2 would be beneficial for most end-users. The current work evaluates the CO2 uptake properties (thermogravimetry study) of low-cost adsorbent materials produced from the animal wastes generated in the livestock area itself, specifically via pyrolysis of poorly biodegradable materials, such as meat and bone meal, and the digestate from manure anaerobic digestion. Therefore, the new element in this study with respect to other studies found in the literature related to biochar-based CO2 adsorption performance is the presence of high content of pyrolyzed proteins in the adsorbent material. In this work, pyrolyzed chars from both meat and bone meal and co-digested manure have been proven to adsorb CO2 reversibly, and also the chars produced from their representative pure proteins (collagen and soybean protein), which were evaluated as model compounds for a better understanding of the individual performance of proteins. The ultra-microporosity developed in the protein chars during pyrolysis seems to be the main explanation for such CO2 uptake capacities, while neither the BET surface area nor N-functionalities on the char surface can properly explain the observed results. Although the CO2 adsorption capacities of these pristine chars (6\u201341.0 mg CO2\/g char) are far away from data of commercially activated carbons ($sim$80 mg CO2\/g char), this application opens a new via to integrate and valorize these wastes in the circular economy of the primary sector.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('149','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_149\" style=\"display:none;\"><div class=\"tp_abstract_entry\">Biogas generation through anaerobic digestion provides an interesting opportunity to valorize some types of animal waste materials whose management is increasingly complicated by legal and environmental restrictions. To successfully expand anaerobic digestion in livestock areas, operational issues such as digestate management must be addressed in an economical and environmentally sustainable way. Biogas upgrading is another necessary stage before intending it to add-value applications. The high concentration of CO2 in biogas results in a reduced caloric value, so the removal of CO2 would be beneficial for most end-users. The current work evaluates the CO2 uptake properties (thermogravimetry study) of low-cost adsorbent materials produced from the animal wastes generated in the livestock area itself, specifically via pyrolysis of poorly biodegradable materials, such as meat and bone meal, and the digestate from manure anaerobic digestion. Therefore, the new element in this study with respect to other studies found in the literature related to biochar-based CO2 adsorption performance is the presence of high content of pyrolyzed proteins in the adsorbent material. In this work, pyrolyzed chars from both meat and bone meal and co-digested manure have been proven to adsorb CO2 reversibly, and also the chars produced from their representative pure proteins (collagen and soybean protein), which were evaluated as model compounds for a better understanding of the individual performance of proteins. The ultra-microporosity developed in the protein chars during pyrolysis seems to be the main explanation for such CO2 uptake capacities, while neither the BET surface area nor N-functionalities on the char surface can properly explain the observed results. Although the CO2 adsorption capacities of these pristine chars (6\u201341.0 mg CO2\/g char) are far away from data of commercially activated carbons ($sim$80 mg CO2\/g char), this application opens a new via to integrate and valorize these wastes in the circular economy of the primary sector.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('149','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_149\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/10.1016\/J.SCITOTENV.2022.157395\" title=\"DOI de seguimiento:10.1016\/J.SCITOTENV.2022.157395\" target=\"_blank\">doi:10.1016\/J.SCITOTENV.2022.157395<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('149','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Bourgalais, J\u00e9r\u00e9my;  Carstensen, Hans-Heinrich;  Herbinet, Olivier;  Garcia, Gustavo A.;  Arnoux, Philippe;  Tran, Luc-Sy;  Vanhove, Guillaume;  Nahon, Laurent;  Hochlaf, Majdi;  Battin-Leclerc, Fr\u00e9d\u00e9rique<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('151','tp_links')\" style=\"cursor:pointer;\">Product Identification in the Low-Temperature Oxidation of Cyclohexane Using a Jet-Stirred Reactor in Combination with SVUV-PEPICO Analysis and Theoretical Quantum Calculations<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">The Journal of Physical Chemistry A, <\/span><span class=\"tp_pub_additional_volume\">vol. 126, <\/span><span class=\"tp_pub_additional_number\">no 34, <\/span><span class=\"tp_pub_additional_pages\">pp. 5784\u20135799, <\/span><span class=\"tp_pub_additional_year\">2022<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 1089-5639<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_151\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('151','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_151\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('151','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_151\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('151','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_151\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{Bourgalais2022,<br \/>\r\ntitle = {Product Identification in the Low-Temperature Oxidation of Cyclohexane Using a Jet-Stirred Reactor in Combination with SVUV-PEPICO Analysis and Theoretical Quantum Calculations},<br \/>\r\nauthor = {J\u00e9r\u00e9my Bourgalais and Hans-Heinrich Carstensen and Olivier Herbinet and Gustavo A. Garcia and Philippe Arnoux and Luc-Sy Tran and Guillaume Vanhove and Laurent Nahon and Majdi Hochlaf and Fr\u00e9d\u00e9rique Battin-Leclerc},<br \/>\r\nurl = {https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.jpca.2c04490},<br \/>\r\ndoi = {10.1021\/ACS.JPCA.2C04490\/ASSET\/IMAGES\/MEDIUM\/JP2C04490_0020.GIF},<br \/>\r\nissn = {1089-5639},<br \/>\r\nyear  = {2022},<br \/>\r\ndate = {2022-09-01},<br \/>\r\njournal = {The Journal of Physical Chemistry A},<br \/>\r\nvolume = {126},<br \/>\r\nnumber = {34},<br \/>\r\npages = {5784--5799},<br \/>\r\npublisher = {American Chemical Society (ACS)},<br \/>\r\nabstract = {Cyclohexane oxidation chemistry was investigated using a near-atmospheric pressure jet-stirred reactor at T = 570 K and equivalence ratio \u03d5 = 0.8. Numerous intermediates including hydroperoxides an...},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('151','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_151\" style=\"display:none;\"><div class=\"tp_abstract_entry\">Cyclohexane oxidation chemistry was investigated using a near-atmospheric pressure jet-stirred reactor at T = 570 K and equivalence ratio \u03d5 = 0.8. Numerous intermediates including hydroperoxides an&#8230;<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('151','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_151\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.jpca.2c04490\" title=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.jpca.2c04490\" target=\"_blank\">https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.jpca.2c04490<\/a><\/li><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/10.1021\/ACS.JPCA.2C04490\/ASSET\/IMAGES\/MEDIUM\/JP2C04490_0020.GIF\" title=\"DOI de seguimiento:10.1021\/ACS.JPCA.2C04490\/ASSET\/IMAGES\/MEDIUM\/JP2C04490_0020.GIF\" target=\"_blank\">doi:10.1021\/ACS.JPCA.2C04490\/ASSET\/IMAGES\/MEDIUM\/JP2C04490_0020.GIF<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('151','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Tran, Luc Sy;  Herbinet, Olivier;  Carstensen, Hans-Heinrich;  Battin-Leclerc, Fr\u00e9d\u00e9rique<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('152','tp_links')\" style=\"cursor:pointer;\">Chemical kinetics of cyclic ethers in combustion<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Progress in Energy and Combustion Science, <\/span><span class=\"tp_pub_additional_volume\">vol. 92, <\/span><span class=\"tp_pub_additional_pages\">pp. 101019, <\/span><span class=\"tp_pub_additional_year\">2022<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 0360-1285<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_152\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('152','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_152\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('152','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_152\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('152','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_152\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{Tran2022,<br \/>\r\ntitle = {Chemical kinetics of cyclic ethers in combustion},<br \/>\r\nauthor = {Luc Sy Tran and Olivier Herbinet and Hans-Heinrich Carstensen and Fr\u00e9d\u00e9rique Battin-Leclerc},<br \/>\r\ndoi = {10.1016\/J.PECS.2022.101019},<br \/>\r\nissn = {0360-1285},<br \/>\r\nyear  = {2022},<br \/>\r\ndate = {2022-09-01},<br \/>\r\nurldate = {2022-09-01},<br \/>\r\njournal = {Progress in Energy and Combustion Science},<br \/>\r\nvolume = {92},<br \/>\r\npages = {101019},<br \/>\r\npublisher = {Pergamon},<br \/>\r\nabstract = {Cyclic Ethers (CEs) belong to a class of compounds of importance to understand the chemistry of both the engine auto-ignition of hydrocarbon fuels and the combustion of oxygenated biofuels. This article, divided in six parts, aims at systematically analyzing how up-to-date experimental and theoretical methods were applied to unveil the gas-phase oxidation chemistry of these compounds. The first part gives a brief overview on the significance of CEs as intermediates formed during alkane low-temperature oxidation summarizing its generally accepted chemical mechanism. This part also addresses the role of CEs as potential biofuels derived from lignocellulosic biomass and discusses the production methods of these molecules and their combustion performances in engine. The second part presents the different theoretical methods dedicated to calculate the electronic structure, thermochemical and kinetic data of CEs. The third part introduces the experimental methods used in studies related to CEs with a special focus on mass spectrometry and gas chromatography. The fourth part reviews the experimental and modeling studies related to CE formation during the low-temperature oxidation of linear, branched, cyclic alkanes, alkylbenzenes, olefins, and oxygenated fuels. The fifth part analyses the published work concerning the CE degradation chemistry and highlights the dominant involved reactions. To finish, the sixth part concludes and proposes future research directions.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('152','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_152\" style=\"display:none;\"><div class=\"tp_abstract_entry\">Cyclic Ethers (CEs) belong to a class of compounds of importance to understand the chemistry of both the engine auto-ignition of hydrocarbon fuels and the combustion of oxygenated biofuels. This article, divided in six parts, aims at systematically analyzing how up-to-date experimental and theoretical methods were applied to unveil the gas-phase oxidation chemistry of these compounds. The first part gives a brief overview on the significance of CEs as intermediates formed during alkane low-temperature oxidation summarizing its generally accepted chemical mechanism. This part also addresses the role of CEs as potential biofuels derived from lignocellulosic biomass and discusses the production methods of these molecules and their combustion performances in engine. The second part presents the different theoretical methods dedicated to calculate the electronic structure, thermochemical and kinetic data of CEs. The third part introduces the experimental methods used in studies related to CEs with a special focus on mass spectrometry and gas chromatography. The fourth part reviews the experimental and modeling studies related to CE formation during the low-temperature oxidation of linear, branched, cyclic alkanes, alkylbenzenes, olefins, and oxygenated fuels. The fifth part analyses the published work concerning the CE degradation chemistry and highlights the dominant involved reactions. To finish, the sixth part concludes and proposes future research directions.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('152','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_152\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/10.1016\/J.PECS.2022.101019\" title=\"DOI de seguimiento:10.1016\/J.PECS.2022.101019\" target=\"_blank\">doi:10.1016\/J.PECS.2022.101019<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('152','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><h3 class=\"tp_h3\" id=\"tp_h3_2021\">2021<\/h3><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Bourgalais, J\u00e9r\u00e9my;  Herbinet, Olivier;  Carstensen, Hans-Heinrich;  Debleza, Janney;  Garcia, Gustavo A.;  Arnoux, Philippe;  Tran, Luc Sy;  Vanhove, Guillaume;  Liu, Binzhi;  Wang, Zhandong;  Hochlaf, Majdi;  Nahon, Laurent;  Battin-Leclerc, Fr\u00e9d\u00e9rique<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('160','tp_links')\" style=\"cursor:pointer;\">Jet-Stirred Reactor Study of Low-Temperature Neopentane Oxidation: A Combined Theoretical, Chromatographic, Mass Spectrometric, and PEPICO Analysis<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Energy and Fuels, <\/span><span class=\"tp_pub_additional_volume\">vol. 35, <\/span><span class=\"tp_pub_additional_number\">no 23, <\/span><span class=\"tp_pub_additional_pages\">pp. 19689\u201319704, <\/span><span class=\"tp_pub_additional_year\">2021<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 15205029<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_160\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('160','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_160\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('160','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_160\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('160','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_160\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{Bourgalais2021,<br \/>\r\ntitle = {Jet-Stirred Reactor Study of Low-Temperature Neopentane Oxidation: A Combined Theoretical, Chromatographic, Mass Spectrometric, and PEPICO Analysis},<br \/>\r\nauthor = {J\u00e9r\u00e9my Bourgalais and Olivier Herbinet and Hans-Heinrich Carstensen and Janney Debleza and Gustavo A. Garcia and Philippe Arnoux and Luc Sy Tran and Guillaume Vanhove and Binzhi Liu and Zhandong Wang and Majdi Hochlaf and Laurent Nahon and Fr\u00e9d\u00e9rique Battin-Leclerc},<br \/>\r\nurl = {https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.energyfuels.1c02080},<br \/>\r\ndoi = {10.1021\/ACS.ENERGYFUELS.1C02080\/SUPPL_FILE\/EF1C02080_SI_002.XLSX},<br \/>\r\nissn = {15205029},<br \/>\r\nyear  = {2021},<br \/>\r\ndate = {2021-12-01},<br \/>\r\nurldate = {2021-12-01},<br \/>\r\njournal = {Energy and Fuels},<br \/>\r\nvolume = {35},<br \/>\r\nnumber = {23},<br \/>\r\npages = {19689--19704},<br \/>\r\npublisher = {American Chemical Society},<br \/>\r\nabstract = {The oxidation of neopentane was studied in jet-stirred reactors at atmospheric pressure over a temperature range 500-850 K and $phi$ = 0.5. The products were analyzed with chromatographic, mass spectrometric, and photoelectron spectroscopic setups complemented with theoretical calculations. This combination provides a comparison of photo-ionization mass spectrometry and gas chromatography for the quantification of mole fractions and highlights the relevant differences between them, while mass-tagged photoelectron spectroscopy sheds light onto the isomeric distribution. The new data and corresponding analyses are expected to provide valuable guidance for an extension of the kinetic model and the choice of experimental methods. The main first and second O2-addition products were observed in agreement with the literature (e.g., 3,3-dimethyloxetane, acetone, isobutene, and ?-ketohydroperoxide). The simulated mole fractions of the products using a literature kinetic model were compared to the experimental results. Even though the kinetic model has been validated previously, significant discrepancies between the measured and simulated mole fractions of 2-methylpropanal and methacrolein, two fuel-specific low-temperature oxidation products, were found. Furthermore, some experimentally observed species related to ?-ketohydroperoxide decomposition were not predicted indicating that the model is incomplete. The detection of 2-methylpropanal and formic acid highlighted the importance of the Korcek-type pathway.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('160','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_160\" style=\"display:none;\"><div class=\"tp_abstract_entry\">The oxidation of neopentane was studied in jet-stirred reactors at atmospheric pressure over a temperature range 500-850 K and $phi$ = 0.5. The products were analyzed with chromatographic, mass spectrometric, and photoelectron spectroscopic setups complemented with theoretical calculations. This combination provides a comparison of photo-ionization mass spectrometry and gas chromatography for the quantification of mole fractions and highlights the relevant differences between them, while mass-tagged photoelectron spectroscopy sheds light onto the isomeric distribution. The new data and corresponding analyses are expected to provide valuable guidance for an extension of the kinetic model and the choice of experimental methods. The main first and second O2-addition products were observed in agreement with the literature (e.g., 3,3-dimethyloxetane, acetone, isobutene, and ?-ketohydroperoxide). The simulated mole fractions of the products using a literature kinetic model were compared to the experimental results. Even though the kinetic model has been validated previously, significant discrepancies between the measured and simulated mole fractions of 2-methylpropanal and methacrolein, two fuel-specific low-temperature oxidation products, were found. Furthermore, some experimentally observed species related to ?-ketohydroperoxide decomposition were not predicted indicating that the model is incomplete. The detection of 2-methylpropanal and formic acid highlighted the importance of the Korcek-type pathway.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('160','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_160\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.energyfuels.1c02080\" title=\"https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.energyfuels.1c02080\" target=\"_blank\">https:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.energyfuels.1c02080<\/a><\/li><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/10.1021\/ACS.ENERGYFUELS.1C02080\/SUPPL_FILE\/EF1C02080_SI_002.XLSX\" title=\"DOI de seguimiento:10.1021\/ACS.ENERGYFUELS.1C02080\/SUPPL_FILE\/EF1C02080_SI_002.XLSX\" target=\"_blank\">doi:10.1021\/ACS.ENERGYFUELS.1C02080\/SUPPL_FILE\/EF1C02080_SI_002.XLSX<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('160','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Pelucchi, Matteo;  Arunthanayothin, Suphaporn;  Song, Yu;  Herbinet, Olivier;  Stagni, Alessandro;  Carstensen, Hans-Heinrich;  Faravelli, Tiziano;  Battin-Leclerc, Fr\u00e9d\u00e9rique<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('172','tp_links')\" style=\"cursor:pointer;\">Pyrolysis and combustion chemistry of pyrrole, a reference component for bio-oil surrogates: Jet-stirred reactor experiments and kinetic modeling<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Energy and Fuels, <\/span><span class=\"tp_pub_additional_volume\">vol. 35, <\/span><span class=\"tp_pub_additional_number\">no 9, <\/span><span class=\"tp_pub_additional_pages\">pp. 7265\u20137284, <\/span><span class=\"tp_pub_additional_year\">2021<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 15205029<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_172\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('172','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_172\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('172','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_172\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('172','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_172\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{Pelucchi2021,<br \/>\r\ntitle = {Pyrolysis and combustion chemistry of pyrrole, a reference component for bio-oil surrogates: Jet-stirred reactor experiments and kinetic modeling},<br \/>\r\nauthor = {Matteo Pelucchi and Suphaporn Arunthanayothin and Yu Song and Olivier Herbinet and Alessandro Stagni and Hans-Heinrich Carstensen and Tiziano Faravelli and Fr\u00e9d\u00e9rique Battin-Leclerc},<br \/>\r\nurl = {https:\/\/dx.doi.org\/10.1021\/acs.energyfuels.0c03874},<br \/>\r\ndoi = {10.1021\/acs.energyfuels.0c03874},<br \/>\r\nissn = {15205029},<br \/>\r\nyear  = {2021},<br \/>\r\ndate = {2021-05-01},<br \/>\r\njournal = {Energy and Fuels},<br \/>\r\nvolume = {35},<br \/>\r\nnumber = {9},<br \/>\r\npages = {7265--7284},<br \/>\r\npublisher = {American Chemical Society},<br \/>\r\nabstract = {Fast-pyrolysis bio-oils (FPBOs) obtained from lignocellulosic biomass are gaining attention as sustainable fuels for various applications, including the transport sector and power production. A significant fraction of bio-oils is constituted by nitrogen-containing compounds (N fuels) that should be considered when developing surrogate models for FPBOs. Moreover, the content of N fuels in FPBOs is expected to strongly contribute to the production of nitrogen oxides (NOx) directly from fuel-bound nitrogen (fuel NOx), in addition to the thermal NOx formation pathways typical of high-temperature combustion conditions. This work investigates the pyrolysis and combustion chemistry of pyrrole (C4H5N), a candidate reference fuel component for FPBO surrogate models. Speciation measurements in an atmospheric pressure jet-stirred reactor have been performed for both pyrolysis and oxidation conditions. Pyrolysis experiments have been performed for 1% pyrrole\/helium mixtures over the temperature range T = 925.1200 K. Oxidation experiments were carried out for 1% pyrrole\/oxygen\/helium mixtures at three equivalence ratios ($phi$ = 0.5, 1.0, and 2.0) over the temperature range T = 700. 1200 K. These new data significantly extend the number of experimental targets for kinetic model validation available at present for pyrrole combustion. After a thorough revision of previous theoretical and kinetic modeling studies, a preliminary kinetic model is developed and validated by means of comparison to new experimental data and those previously reported in the literature. The rate of production and sensitivity analyses highlight important pathways deserving further investigations for a better understanding of pyrrole and, more in general, N fuel combustion chemistry. A critical discussion on experimental challenges to be faced when dealing with pyrrole is also reported, encouraging further experimental investigation with advanced diagnostics.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('172','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_172\" style=\"display:none;\"><div class=\"tp_abstract_entry\">Fast-pyrolysis bio-oils (FPBOs) obtained from lignocellulosic biomass are gaining attention as sustainable fuels for various applications, including the transport sector and power production. A significant fraction of bio-oils is constituted by nitrogen-containing compounds (N fuels) that should be considered when developing surrogate models for FPBOs. Moreover, the content of N fuels in FPBOs is expected to strongly contribute to the production of nitrogen oxides (NOx) directly from fuel-bound nitrogen (fuel NOx), in addition to the thermal NOx formation pathways typical of high-temperature combustion conditions. This work investigates the pyrolysis and combustion chemistry of pyrrole (C4H5N), a candidate reference fuel component for FPBO surrogate models. Speciation measurements in an atmospheric pressure jet-stirred reactor have been performed for both pyrolysis and oxidation conditions. Pyrolysis experiments have been performed for 1% pyrrole\/helium mixtures over the temperature range T = 925.1200 K. Oxidation experiments were carried out for 1% pyrrole\/oxygen\/helium mixtures at three equivalence ratios ($phi$ = 0.5, 1.0, and 2.0) over the temperature range T = 700. 1200 K. These new data significantly extend the number of experimental targets for kinetic model validation available at present for pyrrole combustion. After a thorough revision of previous theoretical and kinetic modeling studies, a preliminary kinetic model is developed and validated by means of comparison to new experimental data and those previously reported in the literature. The rate of production and sensitivity analyses highlight important pathways deserving further investigations for a better understanding of pyrrole and, more in general, N fuel combustion chemistry. A critical discussion on experimental challenges to be faced when dealing with pyrrole is also reported, encouraging further experimental investigation with advanced diagnostics.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('172','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_172\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/10.1021\/acs.energyfuels.0c03874\" title=\"https:\/\/dx.doi.org\/10.1021\/acs.energyfuels.0c03874\" target=\"_blank\">https:\/\/dx.doi.org\/10.1021\/acs.energyfuels.0c03874<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('172','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><\/div><div class=\"tablenav\"><div class=\"tablenav-pages\"><span class=\"displaying-num\">18 registros<\/span> <a class=\"page-numbers button disabled\">&laquo;<\/a> <a class=\"page-numbers button disabled\">&lsaquo;<\/a> 1 de 4 <a href=\"https:\/\/gpt.i3a.es\/es\/hans-heinrich-carstensen\/?limit=2&amp;tgid=&amp;yr=&amp;type=&amp;usr=&amp;auth=&amp;tsr=#tppubs\" title=\"p\u00e1gina siguiente\" class=\"page-numbers button\">&rsaquo;<\/a> <a href=\"https:\/\/gpt.i3a.es\/es\/hans-heinrich-carstensen\/?limit=4&amp;tgid=&amp;yr=&amp;type=&amp;usr=&amp;auth=&amp;tsr=#tppubs\" title=\"\u00faltima p\u00e1gina\" class=\"page-numbers button\">&raquo;<\/a> <\/div><\/div><\/div>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div><\/div>\n\n\n<p><\/p>","protected":false},"excerpt":{"rendered":"","protected":false},"author":1,"featured_media":4462,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[238,239],"tags":[],"class_list":["post-4461","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-permanent-members","category-team"],"_links":{"self":[{"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/posts\/4461","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/comments?post=4461"}],"version-history":[{"count":15,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/posts\/4461\/revisions"}],"predecessor-version":[{"id":4539,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/posts\/4461\/revisions\/4539"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/media\/4462"}],"wp:attachment":[{"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/media?parent=4461"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/categories?post=4461"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/tags?post=4461"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}