{"id":4696,"date":"2023-05-25T09:51:41","date_gmt":"2023-05-25T07:51:41","guid":{"rendered":"https:\/\/gpt-dev.i3a.es\/?p=4696"},"modified":"2023-05-25T09:52:27","modified_gmt":"2023-05-25T07:52:27","slug":"miriam-oliva","status":"publish","type":"post","link":"https:\/\/gpt.i3a.es\/es\/miriam-oliva\/","title":{"rendered":"Miriam Oliva"},"content":{"rendered":"<div id=\"pl-gb4696-69ef2c5897ea0\"  class=\"panel-layout\" ><div id=\"pg-gb4696-69ef2c5897ea0-0\"  class=\"panel-grid panel-has-style\" ><div class=\"siteorigin-panels-stretch panel-row-style panel-row-style-for-gb4696-69ef2c5897ea0-0\" data-stretch-type=\"full-width-stretch\" ><div id=\"pgc-gb4696-69ef2c5897ea0-0-0\"  class=\"panel-grid-cell\" ><div id=\"panel-gb4696-69ef2c5897ea0-0-0-0\" class=\"so-panel widget widget_sow-hero panel-first-child panel-last-child\" data-index=\"0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-hero so-widget-sow-hero-default-93415d0e2dbf-4696 so-widget-fittext-wrapper\"\n\t\t\t data-fit-text-compressor=\"0.85\"\n\t\t>\t\t\t\t<div class=\"sow-slider-base\" style=\"display: none\" tabindex=\"0\">\n\t\t\t\t\t<ul\n\t\t\t\t\tclass=\"sow-slider-images\"\n\t\t\t\t\tdata-settings=\"{&quot;pagination&quot;:true,&quot;speed&quot;:800,&quot;timeout&quot;:8000,&quot;paused&quot;:false,&quot;pause_on_hover&quot;:false,&quot;swipe&quot;:true,&quot;nav_always_show_desktop&quot;:&quot;&quot;,&quot;nav_always_show_mobile&quot;:&quot;&quot;,&quot;breakpoint&quot;:&quot;780px&quot;,&quot;unmute&quot;:false,&quot;anchor&quot;:null}\"\n\t\t\t\t\t\t\t\t\t\tdata-anchor-id=\"\"\n\t\t\t\t>\t\t<li class=\"sow-slider-image\" style=\"visibility: visible;;background-color: #1e73be\" >\n\t\t\t\t\t<div class=\"sow-slider-image-container\">\n\t\t\t<div class=\"sow-slider-image-wrapper\">\n\t\t\t\t<h3 style=\"text-align: center\"><a href=\"..\/team\/\">Investigadores<\/a><\/h3>\n<h1 style=\"text-align: center\"><strong>Miriam Oliva<\/strong><\/h1>\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<\/li>\n\t\t<\/ul>\t\t\t\t<ol class=\"sow-slider-pagination\">\n\t\t\t\t\t\t\t\t\t\t\t<li><a href=\"#\" data-goto=\"0\" aria-label=\"mostrar diapositiva 1\"><\/a><\/li>\n\t\t\t\t\t\t\t\t\t<\/ol>\n\n\t\t\t\t<div class=\"sow-slide-nav sow-slide-nav-next\">\n\t\t\t\t\t<a href=\"#\" data-goto=\"next\" aria-label=\"diapositiva siguiente\" data-action=\"next\">\n\t\t\t\t\t\t<em class=\"sow-sld-icon-thin-right\"><\/em>\n\t\t\t\t\t<\/a>\n\t\t\t\t<\/div>\n\n\t\t\t\t<div class=\"sow-slide-nav sow-slide-nav-prev\">\n\t\t\t\t\t<a href=\"#\" data-goto=\"previous\" aria-label=\"diapositiva anterior\" data-action=\"prev\">\n\t\t\t\t\t\t<em class=\"sow-sld-icon-thin-left\"><\/em>\n\t\t\t\t\t<\/a>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div><\/div><\/div><\/div><\/div><\/div><\/div>\n\n<div id=\"pl-gb4696-69ef2c589898a\"  class=\"panel-layout\" ><div id=\"pg-gb4696-69ef2c589898a-0\"  class=\"panel-grid panel-no-style\" ><div 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\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\trel=\"noopener noreferrer\" \t\t\t\t\t\t\t\t\t\t\t>\n\t\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"37\" height=\"37\" src=\"https:\/\/gpt.i3a.es\/wp-content\/uploads\/2020\/10\/google-scholar.png\" class=\"sow-image-grid-image_html\" alt=\"\" title=\"\" srcset=\"https:\/\/gpt.i3a.es\/wp-content\/uploads\/2020\/10\/google-scholar.png 37w, https:\/\/gpt.i3a.es\/wp-content\/uploads\/2020\/10\/google-scholar-12x12.png 12w\" sizes=\"auto, (max-width: 37px) 100vw, 37px\" \/>\t\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t<\/div>\n<\/div><\/div><\/div><div id=\"panel-gb4696-69ef2c589898a-0-1-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"2\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<blockquote>\n<p><strong>Tel\u00e9fono:<\/strong><\/p>\n<p><strong>Email:<\/strong> miroliva@unizar.es<\/p>\n<p><strong>Address:<\/strong><\/p>\n<\/blockquote>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div>\n\n<div id=\"pl-gb4696-69ef2c589b6e5\"  class=\"panel-layout\" ><div id=\"pg-gb4696-69ef2c589b6e5-0\"  class=\"panel-grid panel-has-style\" ><div class=\"panel-row-style panel-row-style-for-gb4696-69ef2c589b6e5-0\" ><div id=\"pgc-gb4696-69ef2c589b6e5-0-0\"  class=\"panel-grid-cell\" ><div id=\"panel-gb4696-69ef2c589b6e5-0-0-0\" class=\"so-panel widget widget_sow-headline panel-first-child\" data-index=\"0\" ><div class=\"panel-widget-style panel-widget-style-for-gb4696-69ef2c589b6e5-0-0-0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-headline so-widget-sow-headline-default-244eb6bef45a-4696\"\n\t\t\t\n\t\t><div class=\"sow-headline-container\">\n\t\t\t\t\t\t\t<h5 class=\"sow-headline\">\n\t\t\t\t\t\tSOBRE M\u00cd\t\t\t\t\t\t<\/h5>\n\t\t\t\t\t\t\t\t\t\t\t<div class=\"decoration\">\n\t\t\t\t\t\t<div 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Ut enim ad minim veniam, quis nostrud exercitation ullamco laboris nisi ut aliquip ex ea commodo consequat. Duis aute irure dolor in reprehenderit in voluptate velit esse cillum dolore eu fugiat nulla pariatur. Excepteur sint occaecat cupidatat non proident, sunt in culpa qui officia deserunt mollit anim id est laborum .Lorem ipsum dolor sit amet, consectetur.<\/p>\n<p>Lorem ipsum dolor sit amet, consectetur adipiscing elit, sed do eiusmod tempor incididunt ut labore et dolore magna aliqua. Ut enim ad minim veniam, quis nostrud exercitation ullamco laboris nisi ut aliquip ex ea commodo consequat. Duis aute irure dolor in reprehenderit in voluptate velit esse cillum dolore eu fugiat nulla pariatur. Excepteur sint occaecat cupidatat non proident, sunt in culpa qui officia deserunt mollit anim id est laborum .Lorem ipsum dolor sit amet, consectetur.<\/p>\n<p>Lorem ipsum dolor sit amet, consectetur adipiscing elit, sed do eiusmod tempor incididunt ut labore et dolore magna aliqua. Ut enim ad minim veniam, quis nostrud exercitation ullamco laboris nisi ut aliquip ex ea commodo consequat. Duis aute irure dolor in reprehenderit in voluptate velit esse cillum dolore eu fugiat nulla pariatur. 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t\u00e9cnicos<\/option>\r\n                <\/select><\/div><input type=\"hidden\" name=\"trp-form-language\" value=\"es\"\/><\/form><div class=\"tablenav\"><div class=\"tablenav-pages\"><span class=\"displaying-num\">21 registros<\/span> <a class=\"page-numbers button disabled\">&laquo;<\/a> <a class=\"page-numbers button disabled\">&lsaquo;<\/a> 1 de 5 <a href=\"https:\/\/gpt.i3a.es\/es\/miriam-oliva\/?limit=2&amp;tgid=&amp;yr=&amp;type=&amp;usr=&amp;auth=&amp;tsr=#tppubs\" title=\"p\u00e1gina siguiente\" class=\"page-numbers button\">&rsaquo;<\/a> <a href=\"https:\/\/gpt.i3a.es\/es\/miriam-oliva\/?limit=5&amp;tgid=&amp;yr=&amp;type=&amp;usr=&amp;auth=&amp;tsr=#tppubs\" title=\"\u00faltima p\u00e1gina\" class=\"page-numbers button\">&raquo;<\/a> <\/div><\/div><div class=\"teachpress_publication_list\"><h3 class=\"tp_h3\" id=\"tp_h3_2023\">2023<\/h3><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Raso, Raquel;  Lete, Alejandro;  Garc\u00eda, Luc\u00eda;  Ruiz, Joaqu\u00edn;  Oliva, Miriam;  Arauzo, Jes\u00fas<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('507','tp_links')\" style=\"cursor:pointer;\">Aqueous phase hydrogenolysis of glycerol with in situ generated hydrogen over Ni\/Al3Fe1 catalyst: effect of the calcination temperature<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">RSC Advances, <\/span><span class=\"tp_pub_additional_volume\">vol. 13, <\/span><span class=\"tp_pub_additional_number\">no 8, <\/span><span class=\"tp_pub_additional_pages\">pp. 5483\u20135495, <\/span><span class=\"tp_pub_additional_year\">2023<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 2046-2069<\/span><span class=\"tp_pub_additional_note\">, (Publisher: The Royal Society of Chemistry)<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_507\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('507','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_507\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('507','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_507\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('507','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_507\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{raso_aqueous_2023,<br \/>\r\ntitle = {Aqueous phase hydrogenolysis of glycerol with in situ generated hydrogen over Ni\/Al3Fe1 catalyst: effect of the calcination temperature},<br \/>\r\nauthor = {Raquel Raso and Alejandro Lete and Luc\u00eda Garc\u00eda and Joaqu\u00edn Ruiz and Miriam Oliva and Jes\u00fas Arauzo},<br \/>\r\nurl = {https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2023\/ra\/d2ra07929a},<br \/>\r\ndoi = {10.1039\/D2RA07929A},<br \/>\r\nissn = {2046-2069},<br \/>\r\nyear  = {2023},<br \/>\r\ndate = {2023-02-01},<br \/>\r\nurldate = {2023-02-01},<br \/>\r\njournal = {RSC Advances},<br \/>\r\nvolume = {13},<br \/>\r\nnumber = {8},<br \/>\r\npages = {5483\u20135495},<br \/>\r\nabstract = {The present work studied the influence of the calcination temperature on the aqueous phase hydrogenolysis of glycerol with in situ generated hydrogen over a Ni\/Al3Fe1 catalyst. The Ni\/Al3Fe1 catalyst was synthesized by the co-precipitation method at 28 mol% of Ni (Ni\/(Ni + Al + Fe)) and a molar ratio of Al\/Fe of 3\/1. The prepared catalyst was calcined at different temperatures (500\u2013750 \u00b0C). The obtained samples were tested for the aqueous phase hydrogenolysis (APH) of glycerol and characterized by several analytical techniques (ICP-OES, H2-TPR, XRD, N2-physisorption, NH3-TPD, STEM, FESEM, and TGA). The catalyst calcined at 625 \u00b0C was selected as the best sample due to its high acidity, metal dispersion, and catalytic activity; 1,2-propanediol was the highest carbon selectivity product. In addition, it experienced lower metal leaching than the catalyst calcined at 500 \u00b0C.},<br \/>\r\nnote = {Publisher: The Royal Society of Chemistry},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('507','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_507\" style=\"display:none;\"><div class=\"tp_abstract_entry\">The present work studied the influence of the calcination temperature on the aqueous phase hydrogenolysis of glycerol with in situ generated hydrogen over a Ni\/Al3Fe1 catalyst. The Ni\/Al3Fe1 catalyst was synthesized by the co-precipitation method at 28 mol% of Ni (Ni\/(Ni + Al + Fe)) and a molar ratio of Al\/Fe of 3\/1. The prepared catalyst was calcined at different temperatures (500\u2013750 \u00b0C). The obtained samples were tested for the aqueous phase hydrogenolysis (APH) of glycerol and characterized by several analytical techniques (ICP-OES, H2-TPR, XRD, N2-physisorption, NH3-TPD, STEM, FESEM, and TGA). The catalyst calcined at 625 \u00b0C was selected as the best sample due to its high acidity, metal dispersion, and catalytic activity; 1,2-propanediol was the highest carbon selectivity product. In addition, it experienced lower metal leaching than the catalyst calcined at 500 \u00b0C.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('507','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_507\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2023\/ra\/d2ra07929a\" title=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2023\/ra\/d2ra07929a\" target=\"_blank\">https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2023\/ra\/d2ra07929a<\/a><\/li><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/10.1039\/D2RA07929A\" title=\"DOI de seguimiento:10.1039\/D2RA07929A\" target=\"_blank\">doi:10.1039\/D2RA07929A<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('507','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><h3 class=\"tp_h3\" id=\"tp_h3_2021\">2021<\/h3><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Fortea, Jorge;  Garc\u00eda, Luc\u00eda;  Ruiz, Joaqu\u00edn;  Oliva, Miriam;  Arauzo, Jes\u00fas<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('167','tp_links')\" style=\"cursor:pointer;\">An Insight into the Separation of 1,2-Propanediol, Ethylene Glycol, Acetol and Glycerol from an Aqueous Solution by Adsorption on Activated Carbon<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Processes 2021, Vol. 9, Page 1438, <\/span><span class=\"tp_pub_additional_volume\">vol. 9, <\/span><span class=\"tp_pub_additional_number\">no 8, <\/span><span class=\"tp_pub_additional_pages\">pp. 1438, <\/span><span class=\"tp_pub_additional_year\">2021<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 2227-9717<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_167\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('167','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_167\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('167','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_167\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('167','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_167\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{Fortea2021,<br \/>\r\ntitle = {An Insight into the Separation of 1,2-Propanediol, Ethylene Glycol, Acetol and Glycerol from an Aqueous Solution by Adsorption on Activated Carbon},<br \/>\r\nauthor = {Jorge Fortea and Luc\u00eda Garc\u00eda and Joaqu\u00edn Ruiz and Miriam Oliva and Jes\u00fas Arauzo},<br \/>\r\nurl = {https:\/\/www.mdpi.com\/2227-9717\/9\/8\/1438\/htm https:\/\/www.mdpi.com\/2227-9717\/9\/8\/1438},<br \/>\r\ndoi = {10.3390\/PR9081438},<br \/>\r\nissn = {2227-9717},<br \/>\r\nyear  = {2021},<br \/>\r\ndate = {2021-08-01},<br \/>\r\njournal = {Processes 2021, Vol. 9, Page 1438},<br \/>\r\nvolume = {9},<br \/>\r\nnumber = {8},<br \/>\r\npages = {1438},<br \/>\r\npublisher = {Multidisciplinary Digital Publishing Institute},<br \/>\r\nabstract = {Glycerol conversion processes such as aqueous phase reforming and hydrogenolysis generate value-added compounds highly diluted in water. Because distillation is a high energy demand separation step, adsorption could be an attractive alternative to recover these chemicals. Adsorption isotherms of 1,2-propanediol, acetol, ethylene glycol and glycerol onto activated carbon were determined by batch adsorption experiments. These isotherms were fitted slightly better to the Freundlich equation than to the Langmuir equation. Acetol is the compound with the highest adsorption at concentrations smaller than 1 M. Properties of the adsorbate such as the \u2212OH group number, chain length, molecular size and dipole moment, besides characteristics of the adsorbent such as the surface area, oxygen and ash content, are considered to explain the observed results. Moreover, adsorption experiments were performed with mixtures of compounds and it was determined that the molar amount adsorbed is less than predicted from the adsorption isotherms of the individual compounds treated separately. In addition, the influence of the activated carbon thermal pre-treatment temperature on the adsorption capacity has been studied, the optimum being 800 \u00b0C. An analysis of the influence of the activated carbon characteristics showed that the most important parameters are the total pore volume and the ash content.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('167','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_167\" style=\"display:none;\"><div class=\"tp_abstract_entry\">Glycerol conversion processes such as aqueous phase reforming and hydrogenolysis generate value-added compounds highly diluted in water. Because distillation is a high energy demand separation step, adsorption could be an attractive alternative to recover these chemicals. Adsorption isotherms of 1,2-propanediol, acetol, ethylene glycol and glycerol onto activated carbon were determined by batch adsorption experiments. These isotherms were fitted slightly better to the Freundlich equation than to the Langmuir equation. Acetol is the compound with the highest adsorption at concentrations smaller than 1 M. Properties of the adsorbate such as the \u2212OH group number, chain length, molecular size and dipole moment, besides characteristics of the adsorbent such as the surface area, oxygen and ash content, are considered to explain the observed results. Moreover, adsorption experiments were performed with mixtures of compounds and it was determined that the molar amount adsorbed is less than predicted from the adsorption isotherms of the individual compounds treated separately. In addition, the influence of the activated carbon thermal pre-treatment temperature on the adsorption capacity has been studied, the optimum being 800 \u00b0C. An analysis of the influence of the activated carbon characteristics showed that the most important parameters are the total pore volume and the ash content.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('167','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_167\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/www.mdpi.com\/2227-9717\/9\/8\/1438\/htm https:\/\/www.mdpi.com\/2227-9717\/9\/8\/1438\" title=\"https:\/\/www.mdpi.com\/2227-9717\/9\/8\/1438\/htm https:\/\/www.mdpi.com\/2227-9717\/9\/8\/1[...]\" target=\"_blank\">https:\/\/www.mdpi.com\/2227-9717\/9\/8\/1438\/htm https:\/\/www.mdpi.com\/2227-9717\/9\/8\/1[&#8230;]<\/a><\/li><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/10.3390\/PR9081438\" title=\"DOI de seguimiento:10.3390\/PR9081438\" target=\"_blank\">doi:10.3390\/PR9081438<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('167','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Raso, Raquel;  Garc\u00eda, Luc\u00eda;  Ruiz, Joaqu\u00edn;  Oliva, Miriam;  Arauzo, Jes\u00fas<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('175','tp_links')\" style=\"cursor:pointer;\">Aqueous phase hydrogenolysis of glycerol over Ni\/Al-Fe catalysts without external hydrogen addition<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Applied Catalysis B: Environmental, <\/span><span class=\"tp_pub_additional_volume\">vol. 283, <\/span><span class=\"tp_pub_additional_pages\">pp. 119598, <\/span><span class=\"tp_pub_additional_year\">2021<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 09263373<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_175\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('175','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_175\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('175','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_175\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('175','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_175\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{Raso2021,<br \/>\r\ntitle = {Aqueous phase hydrogenolysis of glycerol over Ni\/Al-Fe catalysts without external hydrogen addition},<br \/>\r\nauthor = {Raquel Raso and Luc\u00eda Garc\u00eda and Joaqu\u00edn Ruiz and Miriam Oliva and Jes\u00fas Arauzo},<br \/>\r\ndoi = {10.1016\/j.apcatb.2020.119598},<br \/>\r\nissn = {09263373},<br \/>\r\nyear  = {2021},<br \/>\r\ndate = {2021-04-01},<br \/>\r\njournal = {Applied Catalysis B: Environmental},<br \/>\r\nvolume = {283},<br \/>\r\npages = {119598},<br \/>\r\npublisher = {Elsevier B.V.},<br \/>\r\nabstract = {The present work studied the aqueous phase hydrogenolysis (APH) of glycerol (a by-product of biodiesel manufacturing) without external hydrogen addition to produce value-added products. A series of catalysts based on 28 molar % of Ni were prepared through co-precipitation by changing the Al\/Fe molar ratio. The calcined and used catalysts were characterized by several techniques (ICP-OES, N2-physisorption, XRD, H2-TPR, NH3-TPD, FESEM and STEM). This work examines the effects of the molar ratio of Al\/Fe on the physicochemical characteristics of Ni\/Al-Fe catalysts and during the APH of glycerol. All the catalysts showed low carbon yields to gases and high carbon yields to liquid products, mainly 1,2-propanediol, acetol and ethylene glycol. Ni\/Al3Fe1 catalyst gave the best performance in the APH of glycerol: the highest glycerol conversion (42.31 %), carbon yield to gases (6.57 %) and carbon yield to liquids (30.45%). 1,2-propanediol was the liquid product with the highest carbon selectivity (70.89%).},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('175','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_175\" style=\"display:none;\"><div class=\"tp_abstract_entry\">The present work studied the aqueous phase hydrogenolysis (APH) of glycerol (a by-product of biodiesel manufacturing) without external hydrogen addition to produce value-added products. A series of catalysts based on 28 molar % of Ni were prepared through co-precipitation by changing the Al\/Fe molar ratio. The calcined and used catalysts were characterized by several techniques (ICP-OES, N2-physisorption, XRD, H2-TPR, NH3-TPD, FESEM and STEM). This work examines the effects of the molar ratio of Al\/Fe on the physicochemical characteristics of Ni\/Al-Fe catalysts and during the APH of glycerol. All the catalysts showed low carbon yields to gases and high carbon yields to liquid products, mainly 1,2-propanediol, acetol and ethylene glycol. Ni\/Al3Fe1 catalyst gave the best performance in the APH of glycerol: the highest glycerol conversion (42.31 %), carbon yield to gases (6.57 %) and carbon yield to liquids (30.45%). 1,2-propanediol was the liquid product with the highest carbon selectivity (70.89%).<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('175','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_175\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/10.1016\/j.apcatb.2020.119598\" title=\"DOI de seguimiento:10.1016\/j.apcatb.2020.119598\" target=\"_blank\">doi:10.1016\/j.apcatb.2020.119598<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('175','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Lozano, Pablo;  Sim\u00f3n, Ana I;  Garc\u00eda, Luc\u00eda;  Ruiz, Joaqu\u00edn;  Oliva, Miriam;  Arauzo, Jes\u00fas<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('180','tp_links')\" style=\"cursor:pointer;\">Influence of the Ni-Co\/Al-Mg catalyst loading in the continuous aqueous phase reforming of the bio-oil aqueous fraction<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Processes, <\/span><span class=\"tp_pub_additional_volume\">vol. 9, <\/span><span class=\"tp_pub_additional_number\">no 1, <\/span><span class=\"tp_pub_additional_pages\">pp. 1\u201317, <\/span><span class=\"tp_pub_additional_year\">2021<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 22279717<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_180\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('180','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_180\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('180','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_180\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('180','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_180\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{Lozano2021,<br \/>\r\ntitle = {Influence of the Ni-Co\/Al-Mg catalyst loading in the continuous aqueous phase reforming of the bio-oil aqueous fraction},<br \/>\r\nauthor = {Pablo Lozano and Ana I Sim\u00f3n and Luc\u00eda Garc\u00eda and Joaqu\u00edn Ruiz and Miriam Oliva and Jes\u00fas Arauzo},<br \/>\r\nurl = {https:\/\/doi.org\/10.3390\/pr9010081},<br \/>\r\ndoi = {10.3390\/pr9010081},<br \/>\r\nissn = {22279717},<br \/>\r\nyear  = {2021},<br \/>\r\ndate = {2021-01-01},<br \/>\r\njournal = {Processes},<br \/>\r\nvolume = {9},<br \/>\r\nnumber = {1},<br \/>\r\npages = {1--17},<br \/>\r\npublisher = {MDPI AG},<br \/>\r\nabstract = {The effect of catalyst loading in the Aqueous Phase Reforming (APR) of bio-oil aqueous fraction has been studied with a Ni-Co\/Al-Mg coprecipitated catalyst. Because of the high content of water in the bio-oil aqueous fraction, APR could be a useful process to convert this fraction into valuable products. Experiments of APR with continuous feeding of aqueous solution of acetol, butanol and acetic acid as the only compound, together with a simulated and a real aqueous fraction of bio-oil, were carried out. Liquid products in the liquid effluent of the APR model compounds were quantified and the reaction pathways were revised. The increase of catalyst loading produced an increase of gas production and a gas with higher alkanes content. Acetol was the compound with the highest reactivity while the conversion of acetic acid was very low. The presence of acetic acid in the feed caused catalyst deactivation.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('180','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_180\" style=\"display:none;\"><div class=\"tp_abstract_entry\">The effect of catalyst loading in the Aqueous Phase Reforming (APR) of bio-oil aqueous fraction has been studied with a Ni-Co\/Al-Mg coprecipitated catalyst. Because of the high content of water in the bio-oil aqueous fraction, APR could be a useful process to convert this fraction into valuable products. Experiments of APR with continuous feeding of aqueous solution of acetol, butanol and acetic acid as the only compound, together with a simulated and a real aqueous fraction of bio-oil, were carried out. Liquid products in the liquid effluent of the APR model compounds were quantified and the reaction pathways were revised. The increase of catalyst loading produced an increase of gas production and a gas with higher alkanes content. Acetol was the compound with the highest reactivity while the conversion of acetic acid was very low. The presence of acetic acid in the feed caused catalyst deactivation.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('180','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_180\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/doi.org\/10.3390\/pr9010081\" title=\"https:\/\/doi.org\/10.3390\/pr9010081\" target=\"_blank\">https:\/\/doi.org\/10.3390\/pr9010081<\/a><\/li><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/10.3390\/pr9010081\" title=\"DOI de seguimiento:10.3390\/pr9010081\" target=\"_blank\">doi:10.3390\/pr9010081<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('180','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><h3 class=\"tp_h3\" id=\"tp_h3_2020\">2020<\/h3><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Raso, Raquel;  Garc\u00eda, Lucia;  Ruiz, Joaqu\u00edn;  Oliva, Miriam;  Arauzo, Jes\u00fas<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('195','tp_links')\" style=\"cursor:pointer;\">Study of Ni\/Al-Fe Catalyst Stability in the Aqueous Phase Hydrogenolysis of Glycerol<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Catalysts 2020, Vol. 10, Page 1482, <\/span><span class=\"tp_pub_additional_volume\">vol. 10, <\/span><span class=\"tp_pub_additional_number\">no 12, <\/span><span class=\"tp_pub_additional_pages\">pp. 1482, <\/span><span class=\"tp_pub_additional_year\">2020<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 2073-4344<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_195\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('195','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_195\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('195','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_195\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('195','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_195\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{Raso2020,<br \/>\r\ntitle = {Study of Ni\/Al-Fe Catalyst Stability in the Aqueous Phase Hydrogenolysis of Glycerol},<br \/>\r\nauthor = {Raquel Raso and Lucia Garc\u00eda and Joaqu\u00edn Ruiz and Miriam Oliva and Jes\u00fas Arauzo},<br \/>\r\nurl = {https:\/\/www.mdpi.com\/2073-4344\/10\/12\/1482\/htm https:\/\/www.mdpi.com\/2073-4344\/10\/12\/1482},<br \/>\r\ndoi = {10.3390\/CATAL10121482},<br \/>\r\nissn = {2073-4344},<br \/>\r\nyear  = {2020},<br \/>\r\ndate = {2020-12-01},<br \/>\r\njournal = {Catalysts 2020, Vol. 10, Page 1482},<br \/>\r\nvolume = {10},<br \/>\r\nnumber = {12},<br \/>\r\npages = {1482},<br \/>\r\npublisher = {Multidisciplinary Digital Publishing Institute},<br \/>\r\nabstract = {The present work studied the stability and reusability of Ni\/Al-Fe catalyst in the aqueous phase hydrogenolysis of glycerol without external hydrogen addition. The catalyst based on 28 molar % of Ni with 3\/1 molar ratio of Al\/Fe was prepared through co-precipitation. This catalyst presented the best performance in our last study which compares several Ni\/Al-Fe catalysts with different molar ratios of Al\/Fe. To see the influence of the pressurized water on the physicochemical characteristics of Ni\/Al-Fe catalyst, a test of up to 9 h has been carried out. Fresh and used catalysts were characterized by various techniques: X-ray Diffraction (XRD), N2-physisorption, field emission scanning electron microscopy (FESEM) and STEM. Glycerol conversion and carbon yield to gases and liquids did not vary significantly when compared at 3 h and 9 h. Furthermore, the morphology of the catalyst remains stable after continuous recycling under severe hydrothermal conditions. The nickel rich phase of the catalyst, which was determined by XRD and scanning transmission electron microscopy (STEM) techniques, showed a stable size after 9 h under reaction.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('195','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_195\" style=\"display:none;\"><div class=\"tp_abstract_entry\">The present work studied the stability and reusability of Ni\/Al-Fe catalyst in the aqueous phase hydrogenolysis of glycerol without external hydrogen addition. The catalyst based on 28 molar % of Ni with 3\/1 molar ratio of Al\/Fe was prepared through co-precipitation. This catalyst presented the best performance in our last study which compares several Ni\/Al-Fe catalysts with different molar ratios of Al\/Fe. To see the influence of the pressurized water on the physicochemical characteristics of Ni\/Al-Fe catalyst, a test of up to 9 h has been carried out. Fresh and used catalysts were characterized by various techniques: X-ray Diffraction (XRD), N2-physisorption, field emission scanning electron microscopy (FESEM) and STEM. Glycerol conversion and carbon yield to gases and liquids did not vary significantly when compared at 3 h and 9 h. Furthermore, the morphology of the catalyst remains stable after continuous recycling under severe hydrothermal conditions. The nickel rich phase of the catalyst, which was determined by XRD and scanning transmission electron microscopy (STEM) techniques, showed a stable size after 9 h under reaction.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('195','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_195\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/www.mdpi.com\/2073-4344\/10\/12\/1482\/htm https:\/\/www.mdpi.com\/2073-4344\/10\/12\/1482\" title=\"https:\/\/www.mdpi.com\/2073-4344\/10\/12\/1482\/htm https:\/\/www.mdpi.com\/2073-4344\/10\/[...]\" target=\"_blank\">https:\/\/www.mdpi.com\/2073-4344\/10\/12\/1482\/htm https:\/\/www.mdpi.com\/2073-4344\/10\/[&#8230;]<\/a><\/li><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/10.3390\/CATAL10121482\" title=\"DOI de seguimiento:10.3390\/CATAL10121482\" target=\"_blank\">doi:10.3390\/CATAL10121482<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('195','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><\/div><div class=\"tablenav\"><div class=\"tablenav-pages\"><span class=\"displaying-num\">21 registros<\/span> <a class=\"page-numbers button disabled\">&laquo;<\/a> <a class=\"page-numbers button disabled\">&lsaquo;<\/a> 1 de 5 <a href=\"https:\/\/gpt.i3a.es\/es\/miriam-oliva\/?limit=2&amp;tgid=&amp;yr=&amp;type=&amp;usr=&amp;auth=&amp;tsr=#tppubs\" title=\"p\u00e1gina siguiente\" class=\"page-numbers button\">&rsaquo;<\/a> <a href=\"https:\/\/gpt.i3a.es\/es\/miriam-oliva\/?limit=5&amp;tgid=&amp;yr=&amp;type=&amp;usr=&amp;auth=&amp;tsr=#tppubs\" title=\"\u00faltima p\u00e1gina\" class=\"page-numbers button\">&raquo;<\/a> <\/div><\/div><\/div>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div><\/div>\n\n\n<p><\/p>","protected":false},"excerpt":{"rendered":"","protected":false},"author":1,"featured_media":4700,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[238,239],"tags":[],"class_list":["post-4696","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-permanent-members","category-team"],"_links":{"self":[{"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/posts\/4696","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/comments?post=4696"}],"version-history":[{"count":2,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/posts\/4696\/revisions"}],"predecessor-version":[{"id":4701,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/posts\/4696\/revisions\/4701"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/media\/4700"}],"wp:attachment":[{"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/media?parent=4696"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/categories?post=4696"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/gpt.i3a.es\/es\/wp-json\/wp\/v2\/tags?post=4696"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}