María Atienza-Martínez

@article{villasana_exploring_2023,

title = {Exploring a Low-Cost Valorization Route for Amazonian Cocoa Pod Husks through Thermochemical and Catalytic Upgrading of Pyrolysis Vapors},

author = {Yanet Villasana and Sabino Armenise and Javier Ábrego and María Atienza-Martínez and Karina Hablich and Fernando Bimbela and Alfonso Cornejo and Luis M. Gandía},

url = {https://doi.org/10.1021/acsomega.3c06672},

doi = {10.1021/acsomega.3c06672},

year  = {2023},

date = {2023-10-01},

urldate = {2023-10-01},

journal = {ACS Omega},

volume = {8},

number = {40},

pages = {37610–37621},

abstract = {Ecuador as an international leader in the production of cocoa beans produced more than 300 000 tons in 2021; hence, the management and valorization of the 2 MM tons of waste generated annually by this industry have a strategic and socioeconomic value. Consequently, appropriate technologies to avoid environmental problems and promote sustainable development and the bioeconomy, especially considering that this is a megadiverse country, are of the utmost relevance. For this reason, we explored a low-cost pyrolysis route for valorizing cocoa pod husks from Ecuador’s Amazonian region, aiming at producing pyrolysis liquids (bio-oil), biochar, and gas as an alternative chemical source from cocoa residues in the absence of hydrogen. Downstream catalytic processing of hot pyrolysis vapors using Mo- and/or Ni-based catalysts and standalone γ-Al2O3 was applied for obtaining upgraded bio-oils in a laboratory-scale fixed bed reactor, at 500 °C in a N2 atmosphere. As a result, bimetallic catalysts increased the bio-oil aqueous phase yield by 6.6%, at the expense of the organic phase due to cracking reactions according to nuclear magnetic resonance (NMR) and gas chromatography–mass spectrometry (GC–MS) results. Overall product yield remained constant, in comparison to pyrolysis without any downstream catalytic treatment (bio-oil ∼39.0–40.0 wt % and permanent gases 24.6–26.6 wt %). Ex situ reduced and passivated MoNi/γ-Al2O3 led to the lowest organic phase and highest aqueous phase yields. The product distribution between the two liquid phases was also modified by the catalytic upgrading experiments carried out, according to heteronuclear single-quantum correlation (HSQC), total correlation spectroscopy (TOCSY), and NMR analyses. The detailed composition distribution reported here shows the chemical production potential of this residue and serves as a starting point for subsequent valorizing technologies and/or processes in the food and nonfood industry beneficiating society, environment, economy, and research.},

note = {Publisher: American Chemical Society},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Fonts2021,

title = {Thermodynamic and Physical Property Estimation of Compounds Derived from the Fast Pyrolysis of Lignocellulosic Materials},

author = {Isabel Fonts and María Atienza-Martínez and Hans-Heinrich Carstensen and Mario Benés and Anamaria Paiva Pinheiro Pires and Manuel Garcia-Perez and Rafael Bilbao},

url = {https://pubs.acs.org/doi/full/10.1021/acs.energyfuels.1c01709},

doi = {10.1021/ACS.ENERGYFUELS.1C01709},

year  = {2021},

date = {2021-01-01},

journal = {Energy & Fuels},

publisher = {American Chemical Society},

abstract = {The development of biomass pyrolysis oil refineries is a very promising path for the production of biofuels and bioproducts from lignocellulosic materials. Given that bio-oil is a complex mixture o...},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Atienza-Martinez2020b,

title = {Functionalization of sewage sludge char by partial oxidation with molecular oxygen to enhance its adsorptive properties},

author = {María Atienza-Martínez and Nurull Nadia Binti Suraini and Javier Ábrego and Isabel Fonts and Luisa Lázaro and Hans-Heinrich Carstensen and Gloria Gea},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0959652620352458},

doi = {10.1016/j.jclepro.2020.125201},

issn = {09596526},

year  = {2020},

date = {2020-11-01},

journal = {Journal of Cleaner Production},

pages = {125201},

publisher = {Elsevier},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Arauzo2020b,

title = {Combustion Characteristics of Hydrochar and Pyrochar Derived from Digested Sewage Sludge},

author = {Pablo J Arauzo and María Atienza-Martínez and Javier Ábrego and Maciej P Olszewski and Zebin Cao and Andrea Kruse},

url = {https://www.mdpi.com/1996-1073/13/16/4164},

doi = {10.3390/en13164164},

issn = {1996-1073},

year  = {2020},

date = {2020-08-01},

journal = {Energies},

volume = {13},

number = {16},

pages = {4164},

publisher = {MDPI AG},

abstract = {<p>In this paper, hydrochars and pyrochars were produced at 260 °C under different residence times (2 and 4 h) using anaerobic digested sewage sludge (SSL) as initial feedstock. The effect of reaction time on the fuel properties of hydrochars and pyrochars was evaluated. Moreover, the combustion kinetics of raw SSL and the derived pyrochars and hydrochars without coal blending were determined at two different air flows (20 and 90 mL/min) and compared. In the same conditions, the yield of hydrochar was significantly lower than that of pyrochar, confirming the different reaction pathways followed in each process. The results showed hydrochars have lower carbon recovery and energy yield than pyrochars, making the latter more suitable for energy purposes. The thermogravimetric combustion study showed that both thermochemical treatments increased the ignition temperature but decreased the burnout temperature, which results in higher stability during handling and storage. However, raw SSL is better for combustion than hydrochar according to the combustibility index. In addition, the kinetic study showed that the activation energy of the combustion of biochars, especially pyrochar, is lower than that of raw SSL, which is advantageous for their combustion.</p>},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{Atienza-Martinez2020,

title = {Pyrolysis of dairy cattle manure: evolution of char characteristics},

author = {María Atienza-Martínez and Javier Ábrego and Gloria Gea and Frédéric Marías},

doi = {10.1016/j.jaap.2019.104724},

issn = {01652370},

year  = {2020},

date = {2020-01-01},

journal = {Journal of Analytical and Applied Pyrolysis},

volume = {145},

pages = {104724},

publisher = {Elsevier B.V.},

abstract = {Livestock manure management constitutes a major challenge at this time. Traditionally, this waste has been used as fertilizer. Excessive application of this residual organic matter on agricultural soils can cause soil quality degradation due to heavy metals accumulation, migration of pathogens to water sources and food, and generation of greenhouse gases. As a promising alternative to land application, pyrolysis of livestock manure allows to obtain biochar, bio-oil and syngas. The goal of this work is to study slow pyrolysis of digested dairy cattle manure (DM) both through one-step and multi-step pyrolysis at increasing temperature in the range 250-600 °C. The non-condensable gases composition was continuously analyzed by gas chromatography. Char properties were characterized by ultimate analysis, heavy metals content, ash content, higher heating value (HHV), pH, electrical conductivity (EC), water holding capacity (WHC), cation exchange capacity (CEC), textural properties (specific surface area, pore volume and average pore width) and Fourier Transform Infrared (FTIR) spectroscopy. The experimental results showed that both the product distribution and the properties of char depended on pyrolysis temperature. Char obtained after the last step of multi-step pyrolysis had similar properties to that obtained in one-step pyrolysis. Thus, the cooling and re-heating of the solid between steps did not have a significant effect on the pyrolysis pathway. Pyrolysis at between 400-550 °C allowed to reach a compromise between char pH and electrical conductivity for its potential use as soil amendment.},

keywords = {},

pubstate = {published},

tppubtype = {article}

}